Hmm... if Pledge fills in scratches a tad and there are fewer errors to correct, it might make a tiny difference. But if you can hear that difference, you clearly have a significant disc abuse problem!
And if you know the basic principle and ingredients you shouldn't be surprised. These are nothing less than silicone-based sprays that improve the optical readability of the discs, hence the sound.
Hmm... individual scratches are
very unlikely to cause uncorrectable errors unless they are along the line of the pits, and around approximately 1/3 of the disk circumference or thereabouts. To cause any read error, you'd have to alter a pit length. But to make this significant, you'd have to make it read so incorrectly that the error correction failed completely - quite an undertaking, and usually this requires copious quantities of dust and muck. And, you have to bear in mind that there are plenty of playback errors anyway that
are corrected - so I don't think that scratch removal comes into it at all, quite frankly - a simple wipe clean would suffice.
As for the 'optical readability' claim - well, that comment's a straightforward insult to the Philips and Sony engineers who developed the system. They know full well what the transmission properties of polycarbonate are, and that if you want to improve them, then the only way to do it is with an optical coating that will create a better impedance match between the material and air - in just the same way that a coated lens does on your camera. Polishing a disk with silicon does not provide that coating, and also is likely to reduce the flatness of your disc - both of which effects will make things worse, not better.
It's simple; your player either reads the disk correctly, and the results are as intended, or fails progressively to do so, and after you've got through the correctable errors then you get interpolation or stalling sound.
So, the bottom line, which is important, is -
don't even experiment with this, because it will harm your CDs.
The science behind the other link is
slightly better, but all we are really talking about is the effects of edge diffusion, and a few bits of felt in the appropriate places will take care of this completely. And strictly speaking, it's not just the edge of the speaker you should be concerned with, but also the edges of the cabinet it's in - unless you have speakers specifically designed to prevent this - like most modern monitors. This is why Genelecs are designed the way they are - just to get rid of edge diffraction.